Where the padding goes
A ski boot presses on the shin and calf, so ski socks pad the shin and keep the foot thin for a snug boot. A hiking boot presses underfoot, so hiking socks pad the sole.
Height
Ski socks are always over-the-calf to reach above the boot. The over-the-calf hiking socks here, such as Darn Tough’s Mountaineering, are the ones to try in ski boots.
Using hiking socks for skiing
A thick, full-cushion hiking sock can make a fitted ski boot too tight; choose a lighter one if your boots are snug.
Using ski socks for hiking
With little padding underfoot and a long cuff, a ski sock makes a poor hiking sock for long days on trail.