Three kinds of two-layer sock
A separate liner goes under any hiking sock you own. A liner-and-outer set, like Injinji’s Liner + Hiker, sells the two together. A built-in double layer, like Wrightsock’s Adventure Crew, knits both layers into one sock.
The double-layer page lists every two-layer option side by side.
Check the room for both
Put the liner on, settle the heel and smooth the toes, then the outer sock, then your shoes. If the toes press or the heel slips, the system is too thick for that shoe. Adding a layer is not a way to fill a shoe that is too big either; fix the fit first.
Read both labels
Injinji’s Liner + Hiker pairs a synthetic toe liner with a wool and acrylic outer, so the set is not wool-free. Injinji’s merino toe liner, Smartwool’s Classic Edition Liner and Icebreaker’s Hike+ Liner are wool liners.
Washing and drying two layers
A separate liner washes and dries on its own, so you can rinse liners more often than outers on a trip. A built-in double layer washes and dries as one sock. Follow each maker’s instruction: the care lookup has them.
What this can’t tell you
Makers say liners cut friction, but no sock can promise you will not blister. Try the whole system on a short walk before you rely on it for a long trip.